Send money through the Western Union website. Click the Send Money link on the Western Union homepage. Select Send Online. Fill out the form, and choose how you want to pay. You can either send the money with a credit or debit card, or with your bank account. Step 3: Process the transfer in a Western Union branch. Now you need to decide how to process the transfer - in a branch, online, or on the phone². If you’d rather deal with someone face to face, you can send money via a Western Union office, using cash or sometimes a debit card, depending on the location.². You'll need: 2 Send money for cash pickup^ Return to Top. Log in to your profile. If you don't have a profile, please register for free. Choose country, amount and delivery method (cash). Enter your receiver's name. Pay with your card. You'll get a confirmation by email. Save the tracking number (MTCN) to share with your receiver for pickup.